河野羊一郎らが、鳥取大学と共同で"Electrochemical Anode Behavior of α-FeSi2 Co-Sintered with Solid Electrolyte"を Electrochemistry Vol. 92 issue 1 に執筆
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Electrochemistry
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NASICON-type Li1.5Al0.5Ge1.5(PO4)3 Containing Amorphous Phase for Solid Li-Ion Conductor
Yoichiro KAWANO, Akihiko KATO, Hiroyuki USUI , Yasuhiro DOMI, Hiroki SAKAGUCHI
著者情報
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Yoichiro KAWANO
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University Center for Research on Green Sustainable Chemistry, Tottori University FDK corporation
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Akihiko KATO
FDK corporation
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Hiroyuki USUI
責任著者
https://orcid.org/0000-0002-1156-0340
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University Center for Research on Green Sustainable Chemistry, Tottori University -
Yasuhiro DOMI
https://orcid.org/0000-0003-3983-2202
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University Center for Research on Green Sustainable Chemistry, Tottori University -
Hiroki SAKAGUCHI
責任著者
https://orcid.org/0000-0002-4125-7182
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University Center for Research on Green Sustainable Chemistry, Tottori University
責任著者(Corresponding author)
キーワード: NASICON, Electrochemical Stability, Cyclic Voltammogram, Raman Spectroscopy
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2023 年 91 巻 9 号 p. 097004
DOI https://doi.org/10.5796/electrochemistry.23-00088
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詳細
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Published: 2023/09/29
Received: 2023/09/07
Released on J-STAGE: 2023/09/29
Accepted: 2023/09/08 早期公開日
UNCORRECTED PROOF :2023/09/22
ACCEPTED MANUSCRIPT :2023/09/13
Revised: - -
早期公開記事改版情報
改版日: 2023/09/22 改版理由: 版が更新されました。 改版箇所: 書誌事項,抄録,引用文献,本文PDF 改版内容: -
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ファンド情報
1.助成機関/事業名: Japan Society for the Promotion of Science
助成機関/事業ID:Crossref Funder ID: http://dx.doi.org/10.13039/501100001691
研究費・賞番号:・23H02065
・19K05649
・20H00399
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Amorphous Li1.5Al0.5Ge1.5(PO4)3 (LAGP), which is an oxide-based solid electrolyte with a NASICON-type structure, was sintered at various temperatures to investigate its ionic conductivity and potential windows. The LAGP sheet sintered at 600 °C exhibited a slightly diminished ionic conductivity in comparison to that sintered at 800 °C; however, it effectively suppressed the current density value for oxidative decomposition around 5 V vs. Li+/Li. The crystal structure of the sintered LAGP sheets was confirmed using X-ray diffraction (XRD) and Raman spectroscopy. The results showed that the LAGP sheet sintered at 600 °C contained both crystalline and amorphous phases of LAGP. It was considered that the oxidation resistance of the solid electrolyte was improved by sintering at 600 °C owing to the mixture of crystalline and amorphous phases of LAGP.
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© The Author(s) 2023. Published by ECSJ.
This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium provided the original work is properly cited. [DOI: 10.5796/electrochemistry.23-00088].
http://creativecommons.org/licenses/by/4.0/
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